Search results for " geochemistry"
showing 10 items of 1580 documents
Italica (Seville, Spain): use of local marble in Augustan age
2010
This study concerns 51 marble finds made of “Cipollino verde” coming from the ancient city of Italica (north of the modern city of Santiponce, 9 km NW of Seville, Spain), the earliest Roman settlement in Spain, founded in 206 B.C. The aim of this work was to determine their provenance from Greek and Italian quarries or from local quarries worked in the Iberian Peninsula. Thin-section optical microscopy, X-ray powder diffraction, bulk rock chemistry and O, C and Sr stable isotope analyses were carried out. Results were compared with literature data on “Cipollino verde” marbles quarried in southern Euboea (Greece), Apuan Alps (Italy), Almería, Extremoz, Seville (Spain) and Évora (Portugal). T…
Coupled petrological-geodynamical modeling of a compositionally heterogeneous mantle plume
2018
Abstract Self-consistent geodynamic modeling that includes melting is challenging as the chemistry of the source rocks continuously changes as a result of melt extraction. Here, we describe a new method to study the interaction between physical and chemical processes in an uprising heterogeneous mantle plume by combining a geodynamic code with a thermodynamic modeling approach for magma generation and evolution. We pre-computed hundreds of phase diagrams, each of them for a different chemical system. After melt is extracted, the phase diagram with the closest bulk rock chemistry to the depleted source rock is updated locally. The petrological evolution of rocks is tracked via evolving chemi…
Permian-Triassic Osteichthyes (bony fishes): diversity dynamics and body size evolution
2014
The Permian and Triassic were key time intervals in the history of life on Earth. Both periods are marked by a series of biotic crises including the most catastrophic of such events, the end-Permian mass extinction, which eventually led to a major turnover from typical Palaeozoic faunas and floras to those that are emblematic for the Mesozoic and Cenozoic. Here we review patterns in Permian-Triassic bony fishes, a group whose evolutionary dynamics are understudied. Based on data from primary literature, we analyse changes in their taxonomic diversity and body size (as a proxy for trophic position) and explore their response to Permian-Triassic events. Diversity and body size are investigate…
Characterisation of the magmatic signature in gas emissions from Turrialba Volcano, Costa Rica
2014
The equilibrium composition of volcanic gases with their magma is often overprinted by interaction with a shallow hydrothermal system. Identifying the magmatic signature of volcanic gases is critical to relate their composition to properties of the magma (temperature, fO2, gas-melt segregation depth). We report measurements of the chemical composition and flux of the major gas species emitted from Turrialba Volcano during March 2013. Measurements were made of two vents in the summit region, one of which opened in 2010 and the other in 2012. We determined an average SO2 flux of 5.2 ± 1.9 kg s-1 using scanning ultraviolet spectroscopy, and molar proportions of H2O, CO2, SO2, HCl, CO and H2 ga…
Active Degassing of Deeply Sourced Fluids in Central Europe: New Evidences From a Geochemical Study in Serbia
2021
We report on the results of an extensive geochemical survey of fluids released in the Vardar zone (central-western Serbia), a mega-suture zone at the boundary between Eurasia and Africa plates. Thirty-one bubbling gas samples are investigated for their chemical and isotopic compositions (He, C, Ar) and cluster into three distinct groups (CO2-dominated, N2-dominated, and CH4-dominated) based on the dominant gas species. The measured He isotope ratios range from 0.08 to 1.19 Ra (where Ra is the atmospheric ratio), and reveal for the first time the presence of a minor (<20%) but detectable regional mantle-derived component in Serbia. δ13C values range from −20.2‰ to −0.1‰ (versus PDB), with…
Foreword for the thematic volume of the 8ISCPP. Recent advances in present and past cephalopod studies.
2012
3 pages, éditorial.; International audience
Hydrothermal circulation on Ischia Island (Southern Italy), revealed by an integrated geochemical, geophysical and geological approach
2011
Volcano-hosted hydrothermal systems are complex geological objects, whose thorough characterisation requires extensive and interdisciplinary work. Indeed, even thought geological, geochemical and geophysical observations offer highly significant but independent information, only an integrated multidisciplinary approach can yield a comprehensive characterisation of the chemical/physical structure of hydrothermal systems. Notwithstanding the extensive application of geological, geochemical and geophysical techniques in geothermal research, there are only a few examples in the literature of concurrent use of the three techniques [Finizola et al., 2002; Zlotnicki et al., 2009]; these studies ov…
Crystallization of late-stage MORB under varying water activities and redox conditions: Implications for the formation of highly evolved lavas and ox…
2018
Abstract In order to understand late magmatic processes that occur in the deep oceanic crust, we performed a phase-equilibria study in a representative late-stage system at a pressure of 200 MPa with a special focus on the role of water and oxygen fugacity. The starting composition for the experiments was evaluated based on a statistical approach using evolved fresh MORB glasses from the database PETDB highest in FeO and TiO2 (in average 17.92 wt% and 3.73 wt%, respectively), assumed to represent frozen liquids erupted at the seafloor generated by extensive differentiation of MORB. We conducted crystallization experiments in a range of temperatures from 850 to 1050 °C with water activities …
Experimental alteration of granitic rocks: Implications for the evolution of geothermal brines in the Upper Rhine Graben, Germany
2020
Abstract Geothermal energy exploitation in the Upper Rhine Graben (URG) chiefly has targeted faults and fractures within or connected with the crystalline basement, where hot fluids of c. 200 °C circulate at depths of c. 5 km. Formation fluids of the crystalline basement are highly saline, NaCl-dominated brines, whereas shallow crystalline basement water ( The trace element concentrations of the leachates are hereby related to the composition and stability of minerals in the rocks and can be directly linked to the proposed and observed dissolution processes at the different temperatures. In experiments with pure water at 70 °C, representing the recharge or infiltration conditions, water-roc…
Challenging Darwin: Evolution of Triassic Conodonts and Their Struggle for Life in a Changing World
2017
Abstract The phylogeny and distribution of Triassic conodonts reveal many aspects of their natural history. Conodonts incorporate the morphologic response to temperature as well as to eustatic cycles. Speciation, radiation, and extinction are not fortuitous and evolution uses heterochrony (progenesis and neoteny) in response to stress-generating events. Proteromorphosis (reappearance of ancestral morphs) and paedomorphosis (retention of juvenile traits) is a reaction to sublethal environmental stress. This often follows radiation of fully developed forms in the recovery stage after extinction that timely matches transgressions. Evolutionary retrogradation (neoteny) during eustatic high stan…